Palladium(ii) N-heterocyclic allenylidene complexes with extended intercationic Pd Pd interactions and MMLCT phosphorescenceElectronic supplementary information (ESI) available: Experiment details, additional spectra and tables. CCDC 1825616 and 1825617. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8cc01652f
Extended intercationic Pd Pd contacts of 3.30 Å in the crystal structure and distinct MMLCT transitions absorbing at 528 nm and emitting beyond 600 nm in solutions have been revealed with cyclometalated Pd( ii ) N-heterocyclic allenylidene complexes. The Pd( ii )-based MMLCT excited states are respo...
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| Format | Journal Article |
| Published |
22.05.2018
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| Abstract | Extended intercationic Pd Pd contacts of 3.30 Å in the crystal structure and distinct MMLCT transitions absorbing at 528 nm and emitting beyond 600 nm in solutions have been revealed with cyclometalated Pd(
ii
) N-heterocyclic allenylidene complexes. The Pd(
ii
)-based MMLCT excited states are responsive to concentrations, temperatures, mechanical force and organic vapors.
Pallas's shine: extended intercationic Pd Pd contacts of 3.30 Å show distinct MMLCT transitions and low-energy emissions. |
|---|---|
| AbstractList | Extended intercationic Pd Pd contacts of 3.30 Å in the crystal structure and distinct MMLCT transitions absorbing at 528 nm and emitting beyond 600 nm in solutions have been revealed with cyclometalated Pd(
ii
) N-heterocyclic allenylidene complexes. The Pd(
ii
)-based MMLCT excited states are responsive to concentrations, temperatures, mechanical force and organic vapors.
Pallas's shine: extended intercationic Pd Pd contacts of 3.30 Å show distinct MMLCT transitions and low-energy emissions. |
| Author | Lin, Jinqiang Lu, Wei Suo, Sa Chang, Xiaoyong Zou, Chao Xie, Mo |
| AuthorAffiliation | Department of Chemistry South University of Science and Technology of China Wuhan University College of Chemistry and Molecular Sciences |
| AuthorAffiliation_xml | – name: South University of Science and Technology of China – name: Department of Chemistry – name: Wuhan University – name: College of Chemistry and Molecular Sciences |
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| Notes | For ESI and crystallographic data in CIF or other electronic format see DOI 10.1039/c8cc01652f and 1825617 Electronic supplementary information (ESI) available: Experiment details, additional spectra and tables. CCDC 1825616 |
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| Title | Palladium(ii) N-heterocyclic allenylidene complexes with extended intercationic Pd Pd interactions and MMLCT phosphorescenceElectronic supplementary information (ESI) available: Experiment details, additional spectra and tables. CCDC 1825616 and 1825617. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8cc01652f |
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