Palladium(ii) N-heterocyclic allenylidene complexes with extended intercationic Pd Pd interactions and MMLCT phosphorescenceElectronic supplementary information (ESI) available: Experiment details, additional spectra and tables. CCDC 1825616 and 1825617. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8cc01652f

Extended intercationic Pd Pd contacts of 3.30 Å in the crystal structure and distinct MMLCT transitions absorbing at 528 nm and emitting beyond 600 nm in solutions have been revealed with cyclometalated Pd( ii ) N-heterocyclic allenylidene complexes. The Pd( ii )-based MMLCT excited states are respo...

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Main Authors Zou, Chao, Lin, Jinqiang, Suo, Sa, Xie, Mo, Chang, Xiaoyong, Lu, Wei
Format Journal Article
Published 22.05.2018
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Summary:Extended intercationic Pd Pd contacts of 3.30 Å in the crystal structure and distinct MMLCT transitions absorbing at 528 nm and emitting beyond 600 nm in solutions have been revealed with cyclometalated Pd( ii ) N-heterocyclic allenylidene complexes. The Pd( ii )-based MMLCT excited states are responsive to concentrations, temperatures, mechanical force and organic vapors. Pallas's shine: extended intercationic Pd Pd contacts of 3.30 Å show distinct MMLCT transitions and low-energy emissions.
Bibliography:For ESI and crystallographic data in CIF or other electronic format see DOI
10.1039/c8cc01652f
and
1825617
Electronic supplementary information (ESI) available: Experiment details, additional spectra and tables. CCDC
1825616
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc01652f