Synthesis and characterization of poly(amide-imide)s derived from a new ortho-functional unsymmetrical dicarboxylic acidElectronic supplementary information (ESI) available. See DOI: 10.1039/c7ra11710h
A new diacid monomer containing an imide ring and a methoxy pendant group, 3-trimellitimido-4-methoxybenzoic acid TMBA , was synthesized and characterized. The diacid was used to synthesize six novel poly(amide-imide)s, ( PAI s), through a polycondensation reaction with different diamines in the pre...
Saved in:
Main Authors | , , , , , |
---|---|
Format | Journal Article |
Published |
02.01.2018
|
Online Access | Get full text |
Cover
Loading…
Summary: | A new diacid monomer containing an imide ring and a methoxy pendant group, 3-trimellitimido-4-methoxybenzoic acid
TMBA
, was synthesized and characterized. The diacid was used to synthesize six novel poly(amide-imide)s, (
PAI
s), through a polycondensation reaction with different diamines in the presence of triphenylphosphite, calcium chloride, and pyridine in
N
-methyl-2-pyrrolidinone. The chemical structures of the diacid monomer and poly(amide-imide)s were confirmed by FTIR and
1
H NMR spectroscopy. All
PAI
s were obtained in high yield with inherent viscosities ranging from 0.32 to 0.54 dL g
−1
. They were soluble in aprotic solvents, and exhibited film forming ability. The
PAI
films displayed glass transition temperatures between 281 and 377 °C, as determined by dynamic mechanical analysis, and they show high thermal stability. Gas permeability results for
TMBA-6FDA
film show that this
PAI
could be an interesting material for polymeric membranes aimed to CO
2
separation process.
Herein, we report a new diacid monomer containing an imide ring and a methoxy pendant group, 3-trimellitimido-4-methoxybenzoic acid TMBA, for the preparation of poly(amide-imide)s. |
---|---|
Bibliography: | 10.1039/c7ra11710h Electronic supplementary information (ESI) available. See DOI |
ISSN: | 2046-2069 |
DOI: | 10.1039/c7ra11710h |