The synthesis of planar chiral pseudo-gem aminophosphine pre-ligands based on [2.2]paracyclophaneElectronic supplementary information (ESI) available. CCDC 1572877. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7ob02393f

The synthesis of three planar chiral pseudo-gem disubstituted [2.2]paracyclophane-derived P , N -pre-ligands is reported along with preliminary results of their activity in the amination of aryl bromides and chlorides. The pseudo-gem aminophosphines were capable of mediating the coupling reaction at...

Full description

Saved in:
Bibliographic Details
Main Authors Jayasundera, Krishanthi P, Engels, Tim G. W, Lun, David J, Mungalpara, Maulik N, Plieger, Paul G, Rowlands, Gareth J
Format Journal Article
Published 31.10.2017
Online AccessGet full text

Cover

More Information
Summary:The synthesis of three planar chiral pseudo-gem disubstituted [2.2]paracyclophane-derived P , N -pre-ligands is reported along with preliminary results of their activity in the amination of aryl bromides and chlorides. The pseudo-gem aminophosphines were capable of mediating the coupling reaction at a loading of 1 mol%. We have synthesized three pseudo-gem [2.2]paracyclophane-derived P , N -ligands and report preliminary activity studies for the amination of aryl bromides and chlorides.
Bibliography:Electronic supplementary information (ESI) available. CCDC
For ESI and crystallographic data in CIF or other electronic format see DOI
1572877
10.1039/c7ob02393f
ISSN:1477-0520
1477-0539
DOI:10.1039/c7ob02393f