A new semiconducting 1D Cu(i)-Cu(ii) mixed-valence coordination polymer with Cu(ii) dimethylpiperidine-dithiocarbamate and a tetranuclear Cu(i)-Br cluster unitElectronic supplementary information (ESI) available: Experimental, crystallographic, photoelectron spectroscopy and impedance data. CCDC 1585395. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7nj04763k

A novel mixed-valence coordination polymer [Cu I 4 Cu II Br 4 (dmpip-dtc) 2 (CH 3 CN)] n (dmpip-dtc = dimethylpiperidine-dithiocarbamate) with an infinite one-dimensional structure was synthesized and structurally characterized using X-ray diffraction. The electronic properties of the coordination p...

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Bibliographic Details
Main Authors Himoto, K, Suzuki, S, Okubo, T, Maekawa, M, Kuroda-Sowa, T
Format Journal Article
LanguageEnglish
Published 12.03.2018
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Summary:A novel mixed-valence coordination polymer [Cu I 4 Cu II Br 4 (dmpip-dtc) 2 (CH 3 CN)] n (dmpip-dtc = dimethylpiperidine-dithiocarbamate) with an infinite one-dimensional structure was synthesized and structurally characterized using X-ray diffraction. The electronic properties of the coordination polymer were investigated by UV-vis-NIR spectroscopy. Impedance measurement results demonstrated that this complex has a narrow bandgap, inducing semiconducting behavior. A new 1D semiconducting mixed-valence Cu( i )-Cu( ii ) coordination polymer was synthesized and characterized using impedance measurements.
Bibliography:For ESI and crystallographic data in CIF or other electronic format see DOI
10.1039/c7nj04763k
Electronic supplementary information (ESI) available: Experimental, crystallographic, photoelectron spectroscopy and impedance data. CCDC
1585395
ISSN:1144-0546
1369-9261
DOI:10.1039/c7nj04763k