Compositional introduction of lithium ions into conductive polyoxovanadate-surfactant hybrid crystalsCCDC 1540311 and 1540312. For crystallographic data in CIF or other electronic format see DOI: 10.1039/c7ce00595d
Polyoxovanadate-surfactant hybrid layered crystals were successfully synthesized as single crystals by employing a primary alkylammonium cation, octylammonium ([C 8 H 17 NH 3 ] + , C 8 NH 3 ). Two types of hybrid crystals with the formulae [C 8 H 17 NH 3 ] 6 [V 10 O 28 ]·2H 2 O (C 8 NH 3 -V 10 ) and...
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| Main Authors | , , , , , |
|---|---|
| Format | Journal Article |
| Language | English |
| Published |
05.06.2017
|
| Online Access | Get full text |
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| Summary: | Polyoxovanadate-surfactant hybrid layered crystals were successfully synthesized as single crystals by employing a primary alkylammonium cation, octylammonium ([C
8
H
17
NH
3
]
+
, C
8
NH
3
). Two types of hybrid crystals with the formulae [C
8
H
17
NH
3
]
6
[V
10
O
28
]·2H
2
O (C
8
NH
3
-V
10
) and [C
8
H
17
NH
3
]
4
Li
2
[V
10
O
28
]·4C
2
H
5
OH·6H
2
O (C
8
NH
3
-Li-V
10
) were obtained by different synthetic procedures. Changing the synthetic conditions enabled the precise introduction of lithium cations into the polyoxovanadate-surfactant hybrid crystals according to compositional control. C
8
NH
3
-V
10
contained a discrete [V
10
O
28
]
6−
anion, while C
8
NH
3
-Li-V
10
was composed of a [V
10
O
28
]
6−
anion associated with two lithium cations formulated as {[Li(H
2
O)
3
]
2
[V
10
O
28
]}
4−
. The conductivities of C
8
NH
3
-V
10
and C
8
NH
3
-Li-V
10
were investigated under anhydrous conditions at intermediate temperatures.
The first introduction of lithium cations into polyoxometalate-surfactant hybrid crystals was achieved according to compositional control. |
|---|---|
| Bibliography: | CCDC 1540312 10.1039/c7ce00595d 1540311 and For crystallographic data in CIF or other electronic format see DOI |
| ISSN: | 1466-8033 |
| DOI: | 10.1039/c7ce00595d |