Palladium-catalyzed hydroformylation of terminal arylacetylenes with glyoxylic acidElectronic supplementary information (ESI) available: Experimental procedure and analytical data of hydroformylation products. See DOI: 10.1039/c7cc09629a

A simple, practical and governable palladium-catalyzed hydroformylation of terminal arylacetylenes has been disclosed. The reaction proceeds under syngas-free conditions, using readily available glyoxylic acid as the formyl source, under mild conditions, giving rise to a broad range of α,β-unsaturat...

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Bibliographic Details
Main Authors Liu, Yang, Cai, Liangzhen, Xu, Sheng, Pu, Weiwen, Tao, Xiaochun
Format Journal Article
LanguageEnglish
Published 22.02.2018
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Summary:A simple, practical and governable palladium-catalyzed hydroformylation of terminal arylacetylenes has been disclosed. The reaction proceeds under syngas-free conditions, using readily available glyoxylic acid as the formyl source, under mild conditions, giving rise to a broad range of α,β-unsaturated aldehydes. A reaction process under syngas-free conditions using common ligands and terminal alkyne substrates. The mechanism has been studied.
Bibliography:Electronic supplementary information (ESI) available: Experimental procedure and analytical data of hydroformylation products. See DOI
10.1039/c7cc09629a
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc09629a