Palladium-catalyzed C-H activation/C-C cross-coupling reactions via electrochemistryElectronic supplementary information (ESI) available. CCDC 1550234. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7cc07429h

Palladium-catalyzed C-H activation/C-C cross-coupling reactions typically require stoichiometric chemical oxidants and exogenous ligands. However, there are significant disadvantages associated with the use of traditional stoichiometric oxidants. To overcome these issues, we have developed an electr...

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Main Authors Ma, Cong, Zhao, Chuan-Qi, Li, Yi-Qian, Zhang, Li-Pu, Xu, Xue-Tao, Zhang, Kun, Mei, Tian-Sheng
Format Journal Article
Published 09.11.2017
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Summary:Palladium-catalyzed C-H activation/C-C cross-coupling reactions typically require stoichiometric chemical oxidants and exogenous ligands. However, there are significant disadvantages associated with the use of traditional stoichiometric oxidants. To overcome these issues, we have developed an electrochemical strategy to achieve methylation and acylation. Palladium-catalyzed C(sp 2 )-H methylation and acylation via anodic oxidation have been developed to avoid the use of stoichiometric chemical oxidants.
Bibliography:Electronic supplementary information (ESI) available. CCDC
For ESI and crystallographic data in CIF or other electronic format see DOI
10.1039/c7cc07429h
1550234
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc07429h