A CaMn4O2 model of the biological oxygen evolving complex: synthesis via cluster expansion on a low symmetry ligandElectronic supplementary information (ESI) available: Experimental procedures, characterization data, and crystallographic data (CIF). CCDC 1540537-1540541. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7cc02313h

Using a new multinucleating ligand featuring two dipyridyl alkoxide moieties and a carboxylate moiety, low symmetry tetranuclear complexes 1-M (M = Mn, Fe, and Co) have been synthesized. Complex 1-Mn was used as a precursor for the synthesis of a pentanuclear CaMn 4 O 2 cluster (3) with the same met...

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Bibliographic Details
Main Authors Lee, Heui Beom, Tsui, Emily Y, Agapie, Theodor
Format Journal Article
LanguageEnglish
Published 22.06.2017
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Summary:Using a new multinucleating ligand featuring two dipyridyl alkoxide moieties and a carboxylate moiety, low symmetry tetranuclear complexes 1-M (M = Mn, Fe, and Co) have been synthesized. Complex 1-Mn was used as a precursor for the synthesis of a pentanuclear CaMn 4 O 2 cluster (3) with the same metal stoichiometry as the biological OEC. A pentanuclear CaMn 4 O 2 cluster with the same metal stoichiometry as the biological OEC was prepared from a tetranuclear Mn precursor.
Bibliography:1540537-1540541
For ESI and crystallographic data in CIF or other electronic format see DOI
Electronic supplementary information (ESI) available: Experimental procedures, characterization data, and crystallographic data (CIF). CCDC
10.1039/c7cc02313h
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc02313h