Monodispersed gold nanoparticles supported on a zirconium-based porous metal-organic framework and their high catalytic ability for the reverse water-gas shift reactionElectronic supplementary information (ESI) available. See DOI: 10.1039/c7cc02130e
A highly active and selective Au@UIO-67 catalyst has been assembled. Gold nanoparticles (AuNPs) are monodispersed on the UIO-67 surface of a porous metal-organic framework, the micropores in UIO-67 as templates for adsorbing Au ions and enhancing interaction between AuNPs and UIO-67, favoring the fo...
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| Format | Journal Article |
| Language | English |
| Published |
11.07.2017
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| Online Access | Get full text |
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| Abstract | A highly active and selective Au@UIO-67 catalyst has been assembled. Gold nanoparticles (AuNPs) are monodispersed on the UIO-67 surface of a porous metal-organic framework, the micropores in UIO-67 as templates for adsorbing Au ions and enhancing interaction between AuNPs and UIO-67, favoring the formation of isolated and well-dispersed AuNPs. The catalyst exhibits high catalytic activity and CO selectivity for the reverse water-gas shift reaction in a fixed-bed flow reactor.
A highly active and selective Au@UIO-67 catalyst has been assembled. |
|---|---|
| AbstractList | A highly active and selective Au@UIO-67 catalyst has been assembled. Gold nanoparticles (AuNPs) are monodispersed on the UIO-67 surface of a porous metal-organic framework, the micropores in UIO-67 as templates for adsorbing Au ions and enhancing interaction between AuNPs and UIO-67, favoring the formation of isolated and well-dispersed AuNPs. The catalyst exhibits high catalytic activity and CO selectivity for the reverse water-gas shift reaction in a fixed-bed flow reactor.
A highly active and selective Au@UIO-67 catalyst has been assembled. |
| Author | Xu, Haitao Luo, Xikuo Ge, Jianping Li, Yansong Xu, Zhenliang |
| AuthorAffiliation | Shanghai Key Laboratory of Green Chemistry and Chemical Processes East China University of Science and Technology (ECUST) State Key Laboratory of Chemical Engineering Membrane Science and Engineering R&D Lab School of Chemistry and Molecular Engineering Chemical Engineering Research Center East China Normal University |
| AuthorAffiliation_xml | – name: East China Normal University – name: Membrane Science and Engineering R&D Lab – name: East China University of Science and Technology (ECUST) – name: Chemical Engineering Research Center – name: State Key Laboratory of Chemical Engineering – name: School of Chemistry and Molecular Engineering – name: Shanghai Key Laboratory of Green Chemistry and Chemical Processes |
| Author_xml | – sequence: 1 givenname: Haitao surname: Xu fullname: Xu, Haitao – sequence: 2 givenname: Yansong surname: Li fullname: Li, Yansong – sequence: 3 givenname: Xikuo surname: Luo fullname: Luo, Xikuo – sequence: 4 givenname: Zhenliang surname: Xu fullname: Xu, Zhenliang – sequence: 5 givenname: Jianping surname: Ge fullname: Ge, Jianping |
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| Title | Monodispersed gold nanoparticles supported on a zirconium-based porous metal-organic framework and their high catalytic ability for the reverse water-gas shift reactionElectronic supplementary information (ESI) available. See DOI: 10.1039/c7cc02130e |
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