Monodispersed gold nanoparticles supported on a zirconium-based porous metal-organic framework and their high catalytic ability for the reverse water-gas shift reactionElectronic supplementary information (ESI) available. See DOI: 10.1039/c7cc02130e

A highly active and selective Au@UIO-67 catalyst has been assembled. Gold nanoparticles (AuNPs) are monodispersed on the UIO-67 surface of a porous metal-organic framework, the micropores in UIO-67 as templates for adsorbing Au ions and enhancing interaction between AuNPs and UIO-67, favoring the fo...

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Bibliographic Details
Main Authors Xu, Haitao, Li, Yansong, Luo, Xikuo, Xu, Zhenliang, Ge, Jianping
Format Journal Article
LanguageEnglish
Published 11.07.2017
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Summary:A highly active and selective Au@UIO-67 catalyst has been assembled. Gold nanoparticles (AuNPs) are monodispersed on the UIO-67 surface of a porous metal-organic framework, the micropores in UIO-67 as templates for adsorbing Au ions and enhancing interaction between AuNPs and UIO-67, favoring the formation of isolated and well-dispersed AuNPs. The catalyst exhibits high catalytic activity and CO selectivity for the reverse water-gas shift reaction in a fixed-bed flow reactor. A highly active and selective Au@UIO-67 catalyst has been assembled.
Bibliography:10.1039/c7cc02130e
Electronic supplementary information (ESI) available. See DOI
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc02130e