Distinct activation of Cu-MOR for direct oxidation of methane to methanolElectronic supplementary information (ESI) available: Experimental details, ICP-AES, XRD, TEM, UV-vis-NIR, XANES, TPD of H2O, and free energy calculation. See DOI: 10.1039/c7cc00467b

N 2 O activation of Cu-MOR enhanced methanol production at elevated temperatures, to a greater extent than activation by O 2 under optimal conditions. The increase in methanol production by N 2 O activation was attributed to the facile formation of an active copper center with no formation of inacti...

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Bibliographic Details
Main Authors Kim, Younhwa, Kim, Tae Yong, Lee, Hyunjoo, Yi, Jongheop
Format Journal Article
LanguageEnglish
Published 06.04.2017
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Summary:N 2 O activation of Cu-MOR enhanced methanol production at elevated temperatures, to a greater extent than activation by O 2 under optimal conditions. The increase in methanol production by N 2 O activation was attributed to the facile formation of an active copper center with no formation of inactive intermediate species. Enhancement of methanol production was achieved by N 2 O activation in virtue of the facile formation of active sites at elevated temperatures.
Bibliography:O, and free energy calculation. See DOI
2
Electronic supplementary information (ESI) available: Experimental details, ICP-AES, XRD, TEM, UV-vis-NIR, XANES, TPD of H
10.1039/c7cc00467b
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc00467b