A modular device for large area integrated photoelectrochemical water-splitting as a versatile tool to evaluate photoabsorbers and catalystsElectronic supplementary information (ESI) available. See DOI: 10.1039/c6ta10688a

• Main Authors: Becker, J.-P, Turan, B, Smirnov, V, Welter, K, Urbain, F, Wolff, J, Haas, S, Finger, F
• Format: Journal Article
• Language: English
• Published: 07.03.2017
• ISSN: 2050-7488; 2050-7496
• DOI: 10.1039/c6ta10688a

We present a stand-alone integrated solar water-splitting module with an active area of 64 cm 2 and a long-term stable operation. As a photocathode we employ multijunction thin film silicon solar cells that were optimized to deliver a suitable output voltage for spontaneous water-splitting. Two approaches for the design of a suitable front contact are presented to reduce series resistance losses related to the upscale of the photoelectrodes. The photoelectrode is protected from the electrolyte by a sheet metal which connects the rear contact of the solar cell with the hydrogen evolving catalyst. Thereby, the sheet metal ensures long-term stability while the electrical and thermal coupling of the solar cell and the electrolysis cell is maintained. Due to the modular setup, which allows us to vary and optimize the device components ( i.e. the solar cell, catalysts, membrane, and electrolyte) individually, the presented water-splitting device provides a convenient toolbox for the optimization of such systems. We present a stand-alone integrated solar water-splitting device with an active area of 64 cm 2 and a long-term stable operation. The modular setup of the device provides a versatile tool to integrate and evaluate various combinations of photoelectrodes and catalysts.