TiO2 nanoparticles vs. TiO2 nanowires as support in hydrogen peroxide direct synthesis: the influence of N and Au dopingElectronic supplementary information (ESI) available: Schematic representation of the apparatus (S1), XRD analyses (S2) and XPS Au 4f spectra (S3). See DOI: 10.1039/c6ra24357f

• Main Authors: Gemo, Nicola, Menegazzo, Federica, Biasi, Pierdomenico, Sarkar, Anjana, Samikannu, Ajaikumar, Raut, Dilip G, Kordás, Krisztián, Rautio, Anne-Riikka, Mohl, Melinda, Boström, Dan, Shchukarev, Andrey, Mikkola, Jyri-Pekka
• Format: Journal Article
• Language: English
• Published: 31.10.2016
• ISSN: 2046-2069
• DOI: 10.1039/c6ra24357f

The performance of Pd on titania support were evaluated in the direct synthesis of hydrogen peroxide. The equipment used was a high pressure, semi-batch apparatus equipped with a special injection system. Pd (1 wt%) catalysts on TiO 2 materials with different nature were prepared by wet impregnation method. Three aspects were investigated: (a) the structure of the support (nanoparticles vs. nanowires); (b) the addition of a second active metal (Au); (c) the influence of N-doping of the support. All samples were characterized by means of XPS, TEM and XRD analyses. TiO 2 nanoparticle supported catalyst demonstrated higher H 2 O 2 selectivity and higher turnover frequency (TOF) than the catalysts based on TiO 2 nanowires. The addition of Au to the Pd TiO 2 nanowire catalyst improved the H 2 O 2 selectivity due to altered particle size and electronic effects. Both N-doped versions of the catalysts gave rise to higher H 2 O 2 selectivity than the parent non-doped ones. The synthetic procedure was the source of this observation: larger mean Pd nanoparticles were present, thus favouring the formation of H 2 O 2 as the primary product. Nitrogen doping is a new strategy to improve catalysts for H 2 O 2 direct synthesis.