Mechanochemistry for facilitated access to N,N-diaryl NHC metal complexesElectronic supplementary information (ESI) available: Complete description of mechanosynthetic methods, NMR characterization of compounds. CCDC 1487556. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6nj02895k

A user-friendly and solvent-free mechanosynthetic strategy allowed light-sensitive silver( i ) complexes featuring N , N -diaryl N-heterocyclic carbenes (NHC), including challenging and sterically hindered ligands, to be yielded efficiently. The first transmetalations using ball-milling to obtain pa...

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Bibliographic Details
Main Authors Beillard, Audrey, Bantreil, Xavier, Métro, Thomas-Xavier, Martinez, Jean, Lamaty, Frédéric
Format Journal Article
LanguageEnglish
Published 30.01.2017
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Summary:A user-friendly and solvent-free mechanosynthetic strategy allowed light-sensitive silver( i ) complexes featuring N , N -diaryl N-heterocyclic carbenes (NHC), including challenging and sterically hindered ligands, to be yielded efficiently. The first transmetalations using ball-milling to obtain palladium and copper NHC complexes were performed. A convenient one-pot two-step metalation/transmetalation procedure was also realized. A solvent-free synthesis of NHC-silver, gold, copper and palladium complexes in a ball-mill was achieved.
Bibliography:Electronic supplementary information (ESI) available: Complete description of mechanosynthetic methods, NMR characterization of compounds. CCDC
For ESI and crystallographic data in CIF or other electronic format see DOI
10.1039/c6nj02895k
1487556
ISSN:1144-0546
1369-9261
DOI:10.1039/c6nj02895k