Visible-light-induced release of CO by thiolate iron(iii) carbonyl complexes bearing N,C,S-pincer ligandsElectronic supplementary information (ESI) available: Experimental section, ESR spectra of [1]PF6 and [5]PF6, UV-Vis-NIR spectra of [2]PF6-[4]PF6, ESI-mass and UV-vis spectra during photoreactions, electrochemical data for [1]PF6 and [5]PF6, 1H and 31P{1H} NMR spectra for the one-electron reduced species of [5]PF6, crystallographic data for [1]PF6 and [3]PF6 and computational results. CCDC 14
Iron( iii ) carbonyl complexes are stabilized by a pincer ligand containing pyridine-N, phenyl-C and thiolate-S donors and two axial phosphine ligands. The N,C,S-pincer iron( iii ) carbonyl complexes show CO-releasing properties induced by visible light. Iron( iii ) carbonyl complexes are stabilized...
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| Main Authors | , , , |
|---|---|
| Format | Journal Article |
| Language | English |
| Published |
18.10.2016
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| Online Access | Get full text |
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| Abstract | Iron(
iii
) carbonyl complexes are stabilized by a pincer ligand containing pyridine-N, phenyl-C and thiolate-S donors and two axial phosphine ligands. The N,C,S-pincer iron(
iii
) carbonyl complexes show CO-releasing properties induced by visible light.
Iron(
iii
) carbonyl complexes are stabilized by an N,C,S-pincer ligand and two axial phosphines, showing CO-releasing properties induced by visible light. |
|---|---|
| AbstractList | Iron(
iii
) carbonyl complexes are stabilized by a pincer ligand containing pyridine-N, phenyl-C and thiolate-S donors and two axial phosphine ligands. The N,C,S-pincer iron(
iii
) carbonyl complexes show CO-releasing properties induced by visible light.
Iron(
iii
) carbonyl complexes are stabilized by an N,C,S-pincer ligand and two axial phosphines, showing CO-releasing properties induced by visible light. |
| Author | Nakajima, Hiroshi Nakae, Toyotaka Hirotsu, Masakazu Aono, Shigetoshi |
| AuthorAffiliation | Osaka City University Okazaki Institute for Integrative Bioscience and Institute for Molecular Science National Institutes of Natural Sciences Graduate School of Science Division of Molecular Materials Science |
| AuthorAffiliation_xml | – name: Okazaki Institute for Integrative Bioscience and Institute for Molecular Science – name: Graduate School of Science – name: Division of Molecular Materials Science – name: Osaka City University – name: National Institutes of Natural Sciences |
| Author_xml | – sequence: 1 givenname: Toyotaka surname: Nakae fullname: Nakae, Toyotaka – sequence: 2 givenname: Masakazu surname: Hirotsu fullname: Hirotsu, Masakazu – sequence: 3 givenname: Shigetoshi surname: Aono fullname: Aono, Shigetoshi – sequence: 4 givenname: Hiroshi surname: Nakajima fullname: Nakajima, Hiroshi |
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| DOI | 10.1039/c6dt03399g |
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| Notes | ( Electronic supplementary information (ESI) available: Experimental section, ESR spectra of , - and computational results. CCDC UV-Vis-NIR spectra of P 1496768 1 For ESI and crystallographic data in CIF or other electronic format see DOI 2 3 1496769 4 ESI-mass and UV-vis spectra during photoreactions, electrochemical data for 5 PF 6 and 10.1039/c6dt03399g crystallographic data for H and H} NMR spectra for the one-electron reduced species of 31 |
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| Snippet | Iron(
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| Title | Visible-light-induced release of CO by thiolate iron(iii) carbonyl complexes bearing N,C,S-pincer ligandsElectronic supplementary information (ESI) available: Experimental section, ESR spectra of [1]PF6 and [5]PF6, UV-Vis-NIR spectra of [2]PF6-[4]PF6, ESI-mass and UV-vis spectra during photoreactions, electrochemical data for [1]PF6 and [5]PF6, 1H and 31P{1H} NMR spectra for the one-electron reduced species of [5]PF6, crystallographic data for [1]PF6 and [3]PF6 and computational results. CCDC 14 |
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