Visible-light-induced release of CO by thiolate iron(iii) carbonyl complexes bearing N,C,S-pincer ligandsElectronic supplementary information (ESI) available: Experimental section, ESR spectra of [1]PF6 and [5]PF6, UV-Vis-NIR spectra of [2]PF6-[4]PF6, ESI-mass and UV-vis spectra during photoreactions, electrochemical data for [1]PF6 and [5]PF6, 1H and 31P{1H} NMR spectra for the one-electron reduced species of [5]PF6, crystallographic data for [1]PF6 and [3]PF6 and computational results. CCDC 14

Iron( iii ) carbonyl complexes are stabilized by a pincer ligand containing pyridine-N, phenyl-C and thiolate-S donors and two axial phosphine ligands. The N,C,S-pincer iron( iii ) carbonyl complexes show CO-releasing properties induced by visible light. Iron( iii ) carbonyl complexes are stabilized...

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Bibliographic Details
Main Authors Nakae, Toyotaka, Hirotsu, Masakazu, Aono, Shigetoshi, Nakajima, Hiroshi
Format Journal Article
LanguageEnglish
Published 18.10.2016
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Summary:Iron( iii ) carbonyl complexes are stabilized by a pincer ligand containing pyridine-N, phenyl-C and thiolate-S donors and two axial phosphine ligands. The N,C,S-pincer iron( iii ) carbonyl complexes show CO-releasing properties induced by visible light. Iron( iii ) carbonyl complexes are stabilized by an N,C,S-pincer ligand and two axial phosphines, showing CO-releasing properties induced by visible light.
Bibliography:(
Electronic supplementary information (ESI) available: Experimental section, ESR spectra of
,
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and computational results. CCDC
UV-Vis-NIR spectra of
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For ESI and crystallographic data in CIF or other electronic format see DOI
2
3
1496769
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ESI-mass and UV-vis spectra during photoreactions, electrochemical data for
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PF
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and
10.1039/c6dt03399g
crystallographic data for
H and
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31
ISSN:1477-9226
1477-9234
DOI:10.1039/c6dt03399g