Stability of metal-organic frameworks under gamma irradiationElectronic supplementary information (ESI) available: Synthesis procedures, gamma ray installation and analytical data: powder XRD patterns, BET curves, photos, NMR spectra, and IR spectra. See DOI: 10.1039/c6cc06878b

We report the study of the resistance of archetypal MOFs (MILs, HKUST-1, UiO-66, and ZIF-8) under gamma irradiation. The different porous solids were irradiated with doses up to 1.75 MGy. All the MOFs constructed with transition metals (Cu 2+ , Zn 2+ , Zr 4+ ) exhibit an evident destruction of the f...

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Main Authors Volkringer, C, Falaise, C, Devaux, P, Giovine, R, Stevenson, V, Pourpoint, F, Lafon, O, Osmond, M, Jeanjacques, C, Marcillaud, B, Sabroux, J. C, Loiseau, T
Format Journal Article
LanguageEnglish
Published 13.10.2016
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Summary:We report the study of the resistance of archetypal MOFs (MILs, HKUST-1, UiO-66, and ZIF-8) under gamma irradiation. The different porous solids were irradiated with doses up to 1.75 MGy. All the MOFs constructed with transition metals (Cu 2+ , Zn 2+ , Zr 4+ ) exhibit an evident destruction of the framework, whereas the compounds constructed with aluminium remain intact. We report the study of the resistance of archetypal MOFs (MILs, HKUST-1, UiO-66, and ZIF-8) under gamma irradiation.
Bibliography:Electronic supplementary information (ESI) available: Synthesis procedures, gamma ray installation and analytical data: powder XRD patterns, BET curves, photos, NMR spectra, and IR spectra. See DOI
10.1039/c6cc06878b
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc06878b