Self-templating synthesis of hollow spheres of MOFs and their derived nanostructuresElectronic supplementary information (ESI) available: Experimental details, materials characterization methods and results. See DOI: 10.1039/c6cc05699g

An aqueous one-pot self-templating synthesis method to prepare highly uniform ZIF-67 hollow spheres (ZIF-67-HS) and their transition metal-doped derivatives (M/ZIF-67-HS, M = Cu and/or Zn) was developed. Extension of this approach to another important class of MOFs (metal carboxylates; e.g. , HKUST-...

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Bibliographic Details
Main Authors Chuan Tan, Ying, Chun Zeng, Hua
Format Journal Article
Published 20.09.2016
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Summary:An aqueous one-pot self-templating synthesis method to prepare highly uniform ZIF-67 hollow spheres (ZIF-67-HS) and their transition metal-doped derivatives (M/ZIF-67-HS, M = Cu and/or Zn) was developed. Extension of this approach to another important class of MOFs (metal carboxylates; e.g. , HKUST-1) and facile design of derived nanostructures with complex architectures were also achieved. A facile one-pot aqueous synthetic approach is developed to prepare ZIF-67 hollow spheres under room conditions.
Bibliography:10.1039/c6cc05699g
Electronic supplementary information (ESI) available: Experimental details, materials characterization methods and results. See DOI
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc05699g