NiII tetrahydronorcorroles: antiaromatic porphyrinoids with saturated pyrrole unitsElectronic supplementary information (ESI) available: Synthetic procedures, analytical data of compounds, crystallographic data, and details of DFT calculations. CCDC 1446038. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6cc02918c

While hydrogenated porphyrins are abundant in natural and synthetic compounds, antiaromatic hydrogenated porphyrinoids have not been synthesized to date. Here, we report bacteriochlorin-like Ni II tetrahydronorcorrole complexes as the first examples of antiaromatic porphyrinoids that contain saturat...

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Main Authors Nozawa, Ryo, Yamamoto, Keitaro, Hisaki, Ichiro, Shin, Ji-Young, Shinokubo, Hiroshi
Format Journal Article
Published 24.05.2016
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Summary:While hydrogenated porphyrins are abundant in natural and synthetic compounds, antiaromatic hydrogenated porphyrinoids have not been synthesized to date. Here, we report bacteriochlorin-like Ni II tetrahydronorcorrole complexes as the first examples of antiaromatic porphyrinoids that contain saturated pyrrole units. While hydrogenated porphyrins are abundant in natural and synthetic compounds, antiaromatic hydrogenated porphyrinoids have not been synthesized to date. Here, we report bacteriochlorin-like Ni II tetrahydronorcorrole complexes as the first examples of antiaromatic porphyrinoids that contain saturated pyrrole units.
Bibliography:For ESI and crystallographic data in CIF or other electronic format see DOI
1446038
Electronic supplementary information (ESI) available: Synthetic procedures, analytical data of compounds, crystallographic data, and details of DFT calculations. CCDC
10.1039/c6cc02918c
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc02918c