Unambiguous characterization of anisotropic foldamer packing in a foldecture with an elongated hexagonal plate shapeElectronic supplementary information (ESI) available: Synthetic details, experimental procedures and characterization results. CCDC 1446030. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6cc00502k

Herein we correlate secondary structure perturbation with changes in the solid-state molecular architectures of an elongated hexagonal plate-shaped foldecture derived from the self-assembly of rigid 12-helical β-peptide foldamers to which a flexible C-terminus α-leucine moiety has been appended. Thi...

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Bibliographic Details
Main Authors Yoon, Eunyoung, Gong, Jintaek, Jung, Yoonchul, Lee, Wonchul, Driver, Russell W, Lee, Hee-Seung
Format Journal Article
Published 05.04.2016
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Summary:Herein we correlate secondary structure perturbation with changes in the solid-state molecular architectures of an elongated hexagonal plate-shaped foldecture derived from the self-assembly of rigid 12-helical β-peptide foldamers to which a flexible C-terminus α-leucine moiety has been appended. This study provides the first complete characterization of the directional molecular packing patterns of individual foldamer components within a foldecture, from which a 3D molecular-level picture of the entire foldecture was unambiguously constructed. We report the first complete characterization of the directional molecular packing patterns of individual foldamers within a new foldecture with a well defined hexagonal plate shape.
Bibliography:For ESI and crystallographic data in CIF or other electronic format see DOI
Electronic supplementary information (ESI) available: Synthetic details, experimental procedures and characterization results. CCDC
1446030
10.1039/c6cc00502k
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc00502k