An effective approach to improve the electrochemical performance of LiNi0.6Co0.2Mn0.2O2 cathode by an MOF-derived coatingElectronic supplementary information (ESI) available. See DOI: 10.1039/c5ta10773c

• Main Authors: Li, Siwu, Fu, Xiaotao, Zhou, Junwen, Han, Yuzhen, Qi, Pengfei, Gao, Xing, Feng, Xiao, Wang, Bo
• Format: Journal Article
• Published: 21.04.2016
• ISSN: 2050-7488; 2050-7496
• DOI: 10.1039/c5ta10773c

Herein, we report an effective surface modification for a high energy cathode material, LiNi 0.6 Co 0.2 Mn 0.2 O 2 (NCM-622), using an Al-based MOF (NH 2 -MIL-53), as a precursor to produce MOF-derived alumina (MDA) coatings. The MDA-coating (2.5 wt%) is well-dispersed on the surface of NCM-622 with an amorphous structure. By virtue of the MDA-coating, NCM-622 shows greatly enhanced electrochemical performance: 214.6 mA h g −1 and 196.5 mA h g −1 (3.0-4.5 V vs. Li + /Li) at 0.2C and 1C, respectively, with a capacity retention of 92.7% after 100 cycles at 1C; even at high rates of 5C and 10C, the discharge capacity still approaches 168.5 mA h g −1 and 150.0 mA h g −1 , respectively. We found that these enhancements can be ascribed to the improved structural stability and electrochemical kinetics of NCM-622 by the MDA-coating. We report an effective surface modification for NCM-622, using MOF-derived alumina (MDA) coatings. The coated NCM-622 shows greatly enhanced performance: 214.6 and 196.5 mA h g −1 at 0.2C and 1C, respectively, with capacity retention of 92.7% after 100 cycles at 1C.