Influence of steric bulk on the oxidative stability of phenolate-based magnesium-ion battery electrolytesElectronic supplementary information (ESI) available. See DOI: 10.1039/c5ta07479g

A compilation of electrolytes within the standard R PhOMgCl and AlCl 3 in a THF electrolyte system with varying alkyl-based steric bulks about the phenol ring were prepared and cycled electrochemically. Most notably, 2,4,6-trimethylphenol-based solutions exhibited high conductivity (2.56 mS cm −1 )...

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Main Authors Crowe, Adam J, Bartlett, Bart M
Format Journal Article
Published 22.12.2015
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Abstract A compilation of electrolytes within the standard R PhOMgCl and AlCl 3 in a THF electrolyte system with varying alkyl-based steric bulks about the phenol ring were prepared and cycled electrochemically. Most notably, 2,4,6-trimethylphenol-based solutions exhibited high conductivity (2.56 mS cm −1 ) and compatibility with the Chevrel-phase Mo 6 S 8 intercalation cathode (over 200 h cycle time at C /10 current). A compilation of electrolytes within the standard R PhOMgCl and AlCl 3 in a THF electrolyte system with varying alkyl-based steric bulks about the phenol ring were prepared and cycled electrochemically. For R = 2,4,6-Me 3 , excellent cycling (>200 h cycle life at C /10 current) with Mo 6 S 8 Cheverel is observed.
AbstractList A compilation of electrolytes within the standard R PhOMgCl and AlCl 3 in a THF electrolyte system with varying alkyl-based steric bulks about the phenol ring were prepared and cycled electrochemically. Most notably, 2,4,6-trimethylphenol-based solutions exhibited high conductivity (2.56 mS cm −1 ) and compatibility with the Chevrel-phase Mo 6 S 8 intercalation cathode (over 200 h cycle time at C /10 current). A compilation of electrolytes within the standard R PhOMgCl and AlCl 3 in a THF electrolyte system with varying alkyl-based steric bulks about the phenol ring were prepared and cycled electrochemically. For R = 2,4,6-Me 3 , excellent cycling (>200 h cycle life at C /10 current) with Mo 6 S 8 Cheverel is observed.
Author Bartlett, Bart M
Crowe, Adam J
AuthorAffiliation Department of Chemistry
University of Michigan
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Title Influence of steric bulk on the oxidative stability of phenolate-based magnesium-ion battery electrolytesElectronic supplementary information (ESI) available. See DOI: 10.1039/c5ta07479g
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