Influence of steric bulk on the oxidative stability of phenolate-based magnesium-ion battery electrolytesElectronic supplementary information (ESI) available. See DOI: 10.1039/c5ta07479g
A compilation of electrolytes within the standard R PhOMgCl and AlCl 3 in a THF electrolyte system with varying alkyl-based steric bulks about the phenol ring were prepared and cycled electrochemically. Most notably, 2,4,6-trimethylphenol-based solutions exhibited high conductivity (2.56 mS cm −1 )...
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| Main Authors | , |
|---|---|
| Format | Journal Article |
| Published |
22.12.2015
|
| Online Access | Get full text |
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| Summary: | A compilation of electrolytes within the standard
R
PhOMgCl and AlCl
3
in a THF electrolyte system with varying alkyl-based steric bulks about the phenol ring were prepared and cycled electrochemically. Most notably, 2,4,6-trimethylphenol-based solutions exhibited high conductivity (2.56 mS cm
−1
) and compatibility with the Chevrel-phase Mo
6
S
8
intercalation cathode (over 200 h cycle time at
C
/10 current).
A compilation of electrolytes within the standard
R
PhOMgCl and AlCl
3
in a THF electrolyte system with varying alkyl-based steric bulks about the phenol ring were prepared and cycled electrochemically. For R = 2,4,6-Me
3
, excellent cycling (>200 h cycle life at
C
/10 current) with Mo
6
S
8
Cheverel is observed. |
|---|---|
| Bibliography: | 10.1039/c5ta07479g Electronic supplementary information (ESI) available. See DOI |
| ISSN: | 2050-7488 2050-7496 |
| DOI: | 10.1039/c5ta07479g |