Design and morphology control of a thiophene derivative through electrospraying using various solventsElectronic supplementary information (ESI) available. FESEM images of CF, THF and 12DCE to demonstrate the hollow part inside the microspheres. See DOI: 10.1039/c5ra06468f

• Main Authors: Khanum, Khadija K, S, Sandeep, Ramamurthy, Praveen C
• Format: Journal Article
• Language: English
• Published: 14.07.2015
• ISSN: 2046-2069
• DOI: 10.1039/c5ra06468f

In the present work, electrospraying of an organic molecule is carried out using various solvents, obtaining fibril structures along with a range of distinct morphologies. Solvent characteristics play a major role in determining the morphology of the organic material. A thiophene derivative (7,9-di(thiophen-2-yl)-8 H -cyclopenta[ a ]acenaphthylen-8-one) (DTCPA) of donor-acceptor-donor (DAD) architecture is used to study this solvent effect. Seven solvents with decreasing vapour pressure are selected for experiments. Electrospraying is conducted at a solution concentration of 1.5 wt% and a constant applied voltage of 15 kV. Gradual transformation in morphology of the electrospun product from spiked-spheres to only spikes is observed. A mechanism describing this transformation is proposed based on electron micrograph analysis and XRD analysis. These data indicate that the morphological change is due to the synergistic effect of both vapour pressure and dielectric constant of the solvents. Through a reasonable control of the crystallite size and morphology along with the proposal of the transformation mechanism, this study elucidates electrospraying as a prospective method for designing architectures in organic electronics. A mechanism is proposed for tuning of sphere spike morphology and also control of crystallites size through solvent management using a conjugated molecule.