A concise synthesis of single components of partially sulfated oligomannansElectronic supplementary information (ESI) available: Preparation procedures, references, and spectroscopic data for building blocks 1, 2a, 2a′, 2b, 3, 4-13, and oligomannans 14-21. See DOI: 10.1039/c5ob01786f

A concise synthesis of single components of C2 sulfated oligomannans including trimers, tetramers, and pentamers is reported. The synthesis features the application of the DMF-modulation method for the participatory thiomannoside donors in 1,2- trans α-glycosidic bond formation. The obtained oligoma...

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Bibliographic Details
Main Authors Tony Mong, Kwok-Kong, Shiau, Kai-Sheng, Lin, Yu Hsien, Cheng, Kuang-Chun, Lin, Chun-Hung
Format Journal Article
LanguageEnglish
Published 24.11.2015
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Summary:A concise synthesis of single components of C2 sulfated oligomannans including trimers, tetramers, and pentamers is reported. The synthesis features the application of the DMF-modulation method for the participatory thiomannoside donors in 1,2- trans α-glycosidic bond formation. The obtained oligomannans were fully characterized using 1 H, 13 C, COSY, and HSQC NMR spectroscopy. The synthesis of polysulfated α(1 → 3)/α(1 → 2)-linked oligomannans using the DMF-modulated glycosylation method is reported.
Bibliography:2b
1
3
4-13
14-21
10.1039/c5ob01786f
,
and oligomannans
See DOI
Electronic supplementary information (ESI) available: Preparation procedures, references, and spectroscopic data for building blocks
2a
ISSN:1477-0520
1477-0539
DOI:10.1039/c5ob01786f