Achieving plasmon reproducibility from surfactant free gold nanostar synthesisElectronic supplementary information (ESI) available: Reaction time study, changing silver concentration, concentration matching, altered gold chloride reproducibility. See DOI: 10.1039/c5nj01590a
Obtaining reproducible plasmon resonances from nanostars remains a challenge for both surfactant and surfactant-free syntheses. For any nanostar application, a plasmon band with a reproducible spectral profile and λ max is a fundamental criterion. In particular, synthesis of biocompatible gold nanos...
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Main Authors | , , , , |
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Format | Journal Article |
Language | English |
Published |
23.11.2015
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Online Access | Get full text |
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Summary: | Obtaining reproducible plasmon resonances from nanostars remains a challenge for both surfactant and surfactant-free syntheses. For any nanostar application, a plasmon band with a reproducible spectral profile and
λ
max
is a fundamental criterion. In particular, synthesis of biocompatible gold nanostars will benefit from surfactant-free methods to alleviate concerns over the cytotoxicity of many surfactants used in current synthesis techniques and the relative ease of synthesis. In this paper, we analyze different surfactant-free nanostar synthesis conditions and their influence on achieving plasmon reproducibility. Plasmon reproducibility was judged
via
the standard deviation of the extinction spectra's
λ
max
and the spectral bandwidth. The synthesis temperature was the most influential factor in producing gold nanostars with reproducible plasmons. Nanostars synthesized at 5 °C exhibited a statistically (
α
= 0.05) smaller standard deviation in both their
λ
max
and spectral bandwidth than nanostars synthesized at 25 °C. The reproducibility of the plasmon band was preserved even when the reaction conditions were adjusted to shift the position of the peak plasmon resonance. The high reproducibility of this approach, combined with the ease of synthesis, presents a significant step towards achieving gold nanostars with reproducible plasmons for biological applications. For example, photodynamic therapy, biomedical imaging contrast agents, and biosensing will all benefit from the reproducibility of the nanostars plasmon bands.
The novelty and significance lies in the low temperature synthesis to improve reproducibility of the plasmonic response by a factor of at least two compared to current approaches. |
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Bibliography: | Electronic supplementary information (ESI) available: Reaction time study, changing silver concentration, concentration matching, altered gold chloride reproducibility. See DOI 10.1039/c5nj01590a |
ISSN: | 1144-0546 1369-9261 |
DOI: | 10.1039/c5nj01590a |