Amidino ligands obtained from the coupling of 1-methylcytosine and nitrile: a new method to incorporate biomolecules into luminescent Re(CO)3 complexesElectronic supplementary information (ESI) available: Synthesis and characterization of the complexes, NBO charges and Wiberg indices for 1a, photophysical data, figure of the crystal structure of 2a, frontier molecular orbital compositions in the ground and excited states, and calculated excited energies and dominant orbital excitations from TD-D
The formation of an amidino chelating ligand from the coupling reaction of 1-methylcytosine and nitrile is a new method herein reported for the incorporation of biologically relevant substrates into rhenium( i ) tricarbonyl complexes. The reactions are carried out thermally or are microwave assisted...
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| Format | Journal Article |
| Language | English |
| Published |
06.10.2015
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| Abstract | The formation of an amidino chelating ligand from the coupling reaction of 1-methylcytosine and nitrile is a new method herein reported for the incorporation of biologically relevant substrates into rhenium(
i
) tricarbonyl complexes. The reactions are carried out thermally or are microwave assisted.
Amidino chelating ligands obtained from the coupling of 1-methylcytosine with nitriles allow the incorporation of biologically relevant substrates into Re(CO)
3
complexes. |
|---|---|
| AbstractList | The formation of an amidino chelating ligand from the coupling reaction of 1-methylcytosine and nitrile is a new method herein reported for the incorporation of biologically relevant substrates into rhenium(
i
) tricarbonyl complexes. The reactions are carried out thermally or are microwave assisted.
Amidino chelating ligands obtained from the coupling of 1-methylcytosine with nitriles allow the incorporation of biologically relevant substrates into Re(CO)
3
complexes. |
| Author | Martín-Alvarez, Jose Miguel Gómez-Iglesias, Patricia Villafañe, Fernando Miguel, Daniel |
| AuthorAffiliation | Campus Miguel Delibes Facultad de Ciencias Universidad de Valladolid GIR MIOMeT-IU Cinquima-Química Inorgánica |
| AuthorAffiliation_xml | – name: Universidad de Valladolid – name: Facultad de Ciencias – name: Campus Miguel Delibes – name: GIR MIOMeT-IU Cinquima-Química Inorgánica |
| Author_xml | – sequence: 1 givenname: Patricia surname: Gómez-Iglesias fullname: Gómez-Iglesias, Patricia – sequence: 2 givenname: Jose Miguel surname: Martín-Alvarez fullname: Martín-Alvarez, Jose Miguel – sequence: 3 givenname: Daniel surname: Miguel fullname: Miguel, Daniel – sequence: 4 givenname: Fernando surname: Villafañe fullname: Villafañe, Fernando |
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| ContentType | Journal Article |
| DOI | 10.1039/c5dt03221k |
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| Title | Amidino ligands obtained from the coupling of 1-methylcytosine and nitrile: a new method to incorporate biomolecules into luminescent Re(CO)3 complexesElectronic supplementary information (ESI) available: Synthesis and characterization of the complexes, NBO charges and Wiberg indices for 1a, photophysical data, figure of the crystal structure of 2a, frontier molecular orbital compositions in the ground and excited states, and calculated excited energies and dominant orbital excitations from TD-D |
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