Amidino ligands obtained from the coupling of 1-methylcytosine and nitrile: a new method to incorporate biomolecules into luminescent Re(CO)3 complexesElectronic supplementary information (ESI) available: Synthesis and characterization of the complexes, NBO charges and Wiberg indices for 1a, photophysical data, figure of the crystal structure of 2a, frontier molecular orbital compositions in the ground and excited states, and calculated excited energies and dominant orbital excitations from TD-D
The formation of an amidino chelating ligand from the coupling reaction of 1-methylcytosine and nitrile is a new method herein reported for the incorporation of biologically relevant substrates into rhenium( i ) tricarbonyl complexes. The reactions are carried out thermally or are microwave assisted...
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| Main Authors | , , , |
|---|---|
| Format | Journal Article |
| Language | English |
| Published |
06.10.2015
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| Online Access | Get full text |
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| Summary: | The formation of an amidino chelating ligand from the coupling reaction of 1-methylcytosine and nitrile is a new method herein reported for the incorporation of biologically relevant substrates into rhenium(
i
) tricarbonyl complexes. The reactions are carried out thermally or are microwave assisted.
Amidino chelating ligands obtained from the coupling of 1-methylcytosine with nitriles allow the incorporation of biologically relevant substrates into Re(CO)
3
complexes. |
|---|---|
| Bibliography: | CCDC 1a For ESI and crystallographic data in CIF or other electronic format see DOI frontier molecular orbital compositions in the ground and excited states, and calculated excited energies and dominant orbital excitations from TD-DFT for 10.1039/c5dt03221k and Electronic supplementary information (ESI) available: Synthesis and characterization of the complexes, NBO charges and Wiberg indices for 1415524 1415525 photophysical data, figure of the crystal structure of 2a |
| ISSN: | 1477-9226 1477-9234 |
| DOI: | 10.1039/c5dt03221k |