A self-assembled, multicomponent water oxidation deviceElectronic supplementary information (ESI) available: Experimental details, O2 calibration/quantification; Scheme S1: structure of [Ru(1)3]2+; Fig. S1-S4, S8: SEM images; Fig. S5: complete CVs; Fig. S6: electrochemical reactor; Fig. S7: rate of O2 production under 1 V applied bias; Fig. S9-S13, Table S1: XRD and XPS. See DOI: 10.1039/c5cc09556e
Langmuir-Blodgett (LB) and drop-cast (DC) films prepared from [Ru(1) 3 ][PF 6 ] 2 and Co 4 POM ( 1 = 4,4′-bis( n nonyl)-2,2′-bipyridine, Co 4 POM = K 10 [Co 4 (H 2 O) 2 (α-PW 9 O 34 ) 2 ]) have been evaluated as water oxidation catalysts and their electrocatalytic performances are reported; DC films...
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| Main Authors | , , , , , , , |
|---|---|
| Format | Journal Article |
| Published |
09.02.2016
|
| Online Access | Get full text |
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| Summary: | Langmuir-Blodgett (LB) and drop-cast (DC) films prepared from [Ru(1)
3
][PF
6
]
2
and Co
4
POM (
1
= 4,4′-bis(
n
nonyl)-2,2′-bipyridine, Co
4
POM = K
10
[Co
4
(H
2
O)
2
(α-PW
9
O
34
)
2
]) have been evaluated as water oxidation catalysts and their electrocatalytic performances are reported; DC films evolve more O
2
per unit area than LB films and the catalyst is stable on an FTO surface for 500-600 minutes.
Langmuir-Blodgett (LB) and drop-cast (DC) films of [Ru(
1
)
3
][PF
6
]
2
/Co
4
POM (
1
= 4,4′-bis(
n
nonyl)-2,2′-bipyridine) on FTO function as water oxidation catalysts, and the catalyst evolves O
2
for 600 min. |
|---|---|
| Bibliography: | 1 Fig. S1-S4, S8: SEM images; Fig. S5: complete CVs; Fig. S6: electrochemical reactor; Fig. S7: rate of O 2 3 Electronic supplementary information (ESI) available: Experimental details, O calibration/quantification; Scheme S1: structure of [Ru production under 1 V applied bias; Fig. S9-S13, Table S1: XRD and XPS. See DOI ) 10.1039/c5cc09556e ] |
| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/c5cc09556e |