A one-pot synthesis of polysulfane-bearing block copolymer nanoparticles with tunable size and refractive indexElectronic supplementary information (ESI) available. See DOI: 10.1039/c5cc08490c

A one-pot synthesis of sulfur-rich polymer nanoparticles through a ring-opening metathesis polymerization is reported. The nanoparticles are formed in situ from diblock copolymers containing a polynorbornene derivative bearing cyclic polysulfanes. The refractive indices of the resulting nanoparticle...

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Bibliographic Details
Main Authors Lim, Jeewoo, Cho, Yunshik, Kang, Eun-Hye, Yang, Sanghee, Pyun, Jeffrey, Choi, Tae-Lim, Char, Kookheon
Format Journal Article
Published 02.02.2016
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Summary:A one-pot synthesis of sulfur-rich polymer nanoparticles through a ring-opening metathesis polymerization is reported. The nanoparticles are formed in situ from diblock copolymers containing a polynorbornene derivative bearing cyclic polysulfanes. The refractive indices of the resulting nanoparticles are readily controlled in the range from 1.54 to nearly 1.65. High sulfur-content polysulfane-bearing polymer nanoparticles with tunable size and refractive index were prepared from ROMP.
Bibliography:10.1039/c5cc08490c
Electronic supplementary information (ESI) available. See DOI
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc08490c