Visible-light, photoredox catalyzed, oxidative hydroxylation of arylboronic acids using a metal-organic framework containing tetrakis(carboxyphenyl)porphyrin groupsElectronic supplementary information (ESI) available: Experimental details, XRD, N2 adsorption-desorption, FT-IR, SEM, UV-vis, LFP and TGA measurements. Results of catalytic reactions and a leaching test. See DOI: 10.1039/c5cc06163f
A Zr-based metal-organic framework with tetrakis(carboxyphenyl)porphyrin groups (Zr-MOF-TCPP: MOF-525) has been utilized as a photoredox catalyst to promote oxidative hydroxylation of arylboronic acids under green LED light irradiation. Zr-MOF-TCPP displays a superior catalytic activity for this pro...
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Main Authors | , , , , , , , |
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Format | Journal Article |
Language | English |
Published |
27.10.2015
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Online Access | Get full text |
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