Visible-light, photoredox catalyzed, oxidative hydroxylation of arylboronic acids using a metal-organic framework containing tetrakis(carboxyphenyl)porphyrin groupsElectronic supplementary information (ESI) available: Experimental details, XRD, N2 adsorption-desorption, FT-IR, SEM, UV-vis, LFP and TGA measurements. Results of catalytic reactions and a leaching test. See DOI: 10.1039/c5cc06163f

A Zr-based metal-organic framework with tetrakis(carboxyphenyl)porphyrin groups (Zr-MOF-TCPP: MOF-525) has been utilized as a photoredox catalyst to promote oxidative hydroxylation of arylboronic acids under green LED light irradiation. Zr-MOF-TCPP displays a superior catalytic activity for this pro...

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Bibliographic Details
Main Authors Toyao, Takashi, Ueno, Nana, Miyahara, Kenta, Matsui, Yasunori, Kim, Tae-Ho, Horiuchi, Yu, Ikeda, Hiroshi, Matsuoka, Masaya
Format Journal Article
LanguageEnglish
Published 27.10.2015
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Summary:A Zr-based metal-organic framework with tetrakis(carboxyphenyl)porphyrin groups (Zr-MOF-TCPP: MOF-525) has been utilized as a photoredox catalyst to promote oxidative hydroxylation of arylboronic acids under green LED light irradiation. Zr-MOF-TCPP displays a superior catalytic activity for this process over the corresponding homogeneous catalyst (H 4 TCPP). A Zr-based metal-organic framework with tetrakis(carboxyphenyl)porphyrin groups catalyzes oxidative hydroxylation of arylboronic acids as a photoredox catalyst.
Bibliography:adsorption-desorption, FT-IR, SEM, UV-vis, LFP and TGA measurements. Results of catalytic reactions and a leaching test. See DOI
2
10.1039/c5cc06163f
Electronic supplementary information (ESI) available: Experimental details, XRD, N
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc06163f