Visible-light, photoredox catalyzed, oxidative hydroxylation of arylboronic acids using a metal-organic framework containing tetrakis(carboxyphenyl)porphyrin groupsElectronic supplementary information (ESI) available: Experimental details, XRD, N2 adsorption-desorption, FT-IR, SEM, UV-vis, LFP and TGA measurements. Results of catalytic reactions and a leaching test. See DOI: 10.1039/c5cc06163f

A Zr-based metal-organic framework with tetrakis(carboxyphenyl)porphyrin groups (Zr-MOF-TCPP: MOF-525) has been utilized as a photoredox catalyst to promote oxidative hydroxylation of arylboronic acids under green LED light irradiation. Zr-MOF-TCPP displays a superior catalytic activity for this pro...

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Main Authors Toyao, Takashi, Ueno, Nana, Miyahara, Kenta, Matsui, Yasunori, Kim, Tae-Ho, Horiuchi, Yu, Ikeda, Hiroshi, Matsuoka, Masaya
Format Journal Article
LanguageEnglish
Published 27.10.2015
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Abstract A Zr-based metal-organic framework with tetrakis(carboxyphenyl)porphyrin groups (Zr-MOF-TCPP: MOF-525) has been utilized as a photoredox catalyst to promote oxidative hydroxylation of arylboronic acids under green LED light irradiation. Zr-MOF-TCPP displays a superior catalytic activity for this process over the corresponding homogeneous catalyst (H 4 TCPP). A Zr-based metal-organic framework with tetrakis(carboxyphenyl)porphyrin groups catalyzes oxidative hydroxylation of arylboronic acids as a photoredox catalyst.
AbstractList A Zr-based metal-organic framework with tetrakis(carboxyphenyl)porphyrin groups (Zr-MOF-TCPP: MOF-525) has been utilized as a photoredox catalyst to promote oxidative hydroxylation of arylboronic acids under green LED light irradiation. Zr-MOF-TCPP displays a superior catalytic activity for this process over the corresponding homogeneous catalyst (H 4 TCPP). A Zr-based metal-organic framework with tetrakis(carboxyphenyl)porphyrin groups catalyzes oxidative hydroxylation of arylboronic acids as a photoredox catalyst.
Author Horiuchi, Yu
Ikeda, Hiroshi
Matsuoka, Masaya
Kim, Tae-Ho
Toyao, Takashi
Miyahara, Kenta
Matsui, Yasunori
Ueno, Nana
AuthorAffiliation Division of Mechanics and ICT Convergence Engineering
The Research Institute for Molecular Electronic Devices (RIMED)
Osaka Prefecture University
Department of Applied Chemistry
Sun Moon University
Graduate School of Engineering
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– name: Osaka Prefecture University
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  surname: Miyahara
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  surname: Ikeda
  fullname: Ikeda, Hiroshi
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  givenname: Masaya
  surname: Matsuoka
  fullname: Matsuoka, Masaya
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  publication-title: Handbook of Photochemistry
  doi: Montalti Credi Prodi Gandolfi
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  publication-title: The Chemistry of Phenols
  doi: Rappoport
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Title Visible-light, photoredox catalyzed, oxidative hydroxylation of arylboronic acids using a metal-organic framework containing tetrakis(carboxyphenyl)porphyrin groupsElectronic supplementary information (ESI) available: Experimental details, XRD, N2 adsorption-desorption, FT-IR, SEM, UV-vis, LFP and TGA measurements. Results of catalytic reactions and a leaching test. See DOI: 10.1039/c5cc06163f
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