Synthesis of homochiral tris-indanyl molecular rodsElectronic supplementary information (ESI) available: 1H NMR, 13C NMR, MS, IR spectra for compounds 3-14a. See DOI: 10.1039/c4ob00011k

Homochiral tris-indanyl molecular rods designed for supramolecular surface self-assembly were synthesized. The chiral indanol moiety was constructed via a Ti-mediated alkyne trimerization. Further manipulations resulted in a homochiral indanol monomer. This was employed as the precursor for successi...

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Bibliographic Details
Main Authors Kjeldsen, Niels Due, Funder, Erik Daa, Gothelf, Kurt V
Format Journal Article
LanguageEnglish
Published 14.05.2014
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Summary:Homochiral tris-indanyl molecular rods designed for supramolecular surface self-assembly were synthesized. The chiral indanol moiety was constructed via a Ti-mediated alkyne trimerization. Further manipulations resulted in a homochiral indanol monomer. This was employed as the precursor for successive Sonogashira and Ohira-Bestman reactions towards the homochiral tris-indanyl molecular rods. The molecular rods will be applied for scanning tunnelling microscopy studies of their surface self-assembly and chirality. By Ti-mediated alkyne trimerization and subsequent Sonogashira and Ohira-Bestman reactions, homochiral molecular rod molecules were prepared for surface self-assembly studies.
Bibliography:10.1039/c4ob00011k
1
C NMR, MS, IR spectra for compounds
13
Electronic supplementary information (ESI) available
3-14a
See DOI
H NMR
ISSN:1477-0520
1477-0539
DOI:10.1039/c4ob00011k