Arene-ligated heteroleptic terphenolate complexes of thoriumElectronic supplementary information (ESI) available: Full synthetic and crystallographic details for the complexes. CCDC 1019326-1019329 and 1020471. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4dt02995j

Bulky terphenolate ligands allow the synthesis of rare heteroleptic thorium chloride, and borohydride complexes; in the absence of donor solvents, the terphenolate ligands protect the metal ions through neutral Th-η 6 -arene interactions in a thorium bis(arene) sandwich motif. Bulky terphenolate lig...

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Bibliographic Details
Main Authors McKinven, Jamie, Nichol, Gary S, Arnold, Polly L
Format Journal Article
LanguageEnglish
Published 04.11.2014
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Summary:Bulky terphenolate ligands allow the synthesis of rare heteroleptic thorium chloride, and borohydride complexes; in the absence of donor solvents, the terphenolate ligands protect the metal ions through neutral Th-η 6 -arene interactions in a thorium bis(arene) sandwich motif. Bulky terphenolate ligands allow the synthesis of rare heteroleptic thorium chloride, and borohydride complexes; in the absence of donor solvents, the terphenolate ligands protect the metal ions through neutral Th-η 6 -arene interactions in a thorium bis(arene) sandwich motif.
Bibliography:1020471
For ESI and crystallographic data in CIF or other electronic format see DOI
Electronic supplementary information (ESI) available: Full synthetic and crystallographic details for the complexes. CCDC
and
10.1039/c4dt02995j
1019326-1019329
ISSN:1477-9226
1477-9234
DOI:10.1039/c4dt02995j