A truncated [MnIII12] tetrahedron from oxime-based [MnIII3O] building blocksElectronic supplementary information (ESI) available: Synthetic procedures, crystallographic details and additional magnetic and theoretical data. CCDC 949848. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4dt01469c

The use of the novel pro-ligand H 4 L combining the complimentary phenolic oxime and diethanolamine moieties in one organic framework, results in the formation of the first example of a [Mn III 12 ] truncated tetrahedron and an extremely rare example of a Mn cage conforming to an Archimedean solid....

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Main Authors Frost, J. M, Sanz, S, Rajeshkumar, T, Pitak, M. B, Coles, S. J, Rajaraman, G, Wernsdorfer, W, Schnack, J, Lusby, P. J, Brechin, E. K
Format Journal Article
LanguageEnglish
Published 24.06.2014
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Summary:The use of the novel pro-ligand H 4 L combining the complimentary phenolic oxime and diethanolamine moieties in one organic framework, results in the formation of the first example of a [Mn III 12 ] truncated tetrahedron and an extremely rare example of a Mn cage conforming to an Archimedean solid. The use of the novel pro-ligand H 4 L combining the complimentary phenolic oxime and diethanolamine moieties in one organic framework, results in the formation of the first example of a [Mn III 12 ] truncated tetrahedron.
Bibliography:For ESI and crystallographic data in CIF or other electronic format see DOI
Electronic supplementary information (ESI) available: Synthetic procedures, crystallographic details and additional magnetic and theoretical data. CCDC
949848
10.1039/c4dt01469c
ISSN:1477-9226
1477-9234
DOI:10.1039/c4dt01469c