Gold(iii) compounds containing a chelating, dicarbanionic ligand derived from 4,4′-di-tert-butylbiphenylCCDC 973049, 973050, 973052 and 973053. For crystallographic data in CIF or other electronic format see DOI: 10.1039/c4dt00778f

An oligomeric gold( iii ) compound containing dicarbanionic chelating 4,4′-di- tert -butylbiphenyl was prepared via transmetallation using the corresponding organotin( iv ) compound. The reactivity of the chloro-bridged oligomer with various species including neutral N-, P-, and C-donor ligands as w...

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Bibliographic Details
Main Authors David, B, Monkowius, U, Rust, J, Lehmann, C. W, Hyzak, L, Mohr, F
Format Journal Article
LanguageEnglish
Published 24.06.2014
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Summary:An oligomeric gold( iii ) compound containing dicarbanionic chelating 4,4′-di- tert -butylbiphenyl was prepared via transmetallation using the corresponding organotin( iv ) compound. The reactivity of the chloro-bridged oligomer with various species including neutral N-, P-, and C-donor ligands as well as monoanionic S- and Se-ligands was investigated. Some of the products were characterised by X-ray crystallography. The photophysical properties of two derivatives were studied. Various gold( iii )heterocycles were prepared and their structures and photophysical properties were examined.
Bibliography:CCDC
973049
973050
and
For crystallographic data in CIF or other electronic format see DOI
10.1039/c4dt00778f
973053
973052
,
ISSN:1477-9226
1477-9234
DOI:10.1039/c4dt00778f