Hydrosilylation catalysis by an earth alkaline metal silyl: synthesis, characterization, and reactivity of bis(triphenylsilyl)calciumElectronic supplementary information (ESI) available: Experimental section, details of DFT calculations, NMR spectra, and X-ray crystallographic data. CCDC 963862 (2a) and 963863 (2b). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3cc49308c

Bis(triphenylsilyl)calcium [Ca(SiPh 3 ) 2 (thf)] obtained in high yield as a crystalline ether adduct catalyzes the hydrosilylation of activated C-C double bonds efficiently and regioselectively. Bis(triphenylsilyl)calcium [Ca(SiPh 3 ) 2 (thf)] obtained in high yield as a crystalline ether adduct ca...

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Bibliographic Details
Main Authors Leich, Valeri, Spaniol, Thomas P, Maron, Laurent, Okuda, Jun
Format Journal Article
LanguageEnglish
Published 04.02.2014
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Summary:Bis(triphenylsilyl)calcium [Ca(SiPh 3 ) 2 (thf)] obtained in high yield as a crystalline ether adduct catalyzes the hydrosilylation of activated C-C double bonds efficiently and regioselectively. Bis(triphenylsilyl)calcium [Ca(SiPh 3 ) 2 (thf)] obtained in high yield as a crystalline ether adduct catalyzes the hydrosilylation of activated C-C double bonds efficiently and regioselectively.
Bibliography:2b
For ESI and crystallographic data in CIF or other electronic format see DOI
and
(
963863
10.1039/c3cc49308c
963862
Electronic supplementary information (ESI) available: Experimental section, details of DFT calculations, NMR spectra, and X-ray crystallographic data. CCDC
2a
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc49308c