An insight into the mechanism of the aerobic oxidation of aldehydes catalyzed by N-heterocyclic carbenesElectronic supplementary information (ESI) available: Experimental procedures, mass spectrometric experiments, theoretical calculations and spectra. See DOI: 10.1039/c3cc48929a

N-Heterocyclic carbene catalysis for the aerobic oxidation and esterification of aromatic aldehydes was monitored by ESI-MS (MS/MS) and the key intermediates were intercepted and characterized using the charge-tag strategy. The existence of the key intermediates hypothesized for the N-heterocyclic c...

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Bibliographic Details
Main Authors Bortolini, O, Chiappe, C, Fogagnolo, M, Giovannini, P. P, Massi, A, Pomelli, C. S, Ragno, D
Format Journal Article
LanguageEnglish
Published 28.01.2014
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Summary:N-Heterocyclic carbene catalysis for the aerobic oxidation and esterification of aromatic aldehydes was monitored by ESI-MS (MS/MS) and the key intermediates were intercepted and characterized using the charge-tag strategy. The existence of the key intermediates hypothesized for the N-heterocyclic carbene-catalyzed aerobic oxidation of aldehydes has been proven by ESI-MS (MS) experiments.
Bibliography:Electronic supplementary information (ESI) available: Experimental procedures, mass spectrometric experiments, theoretical calculations and spectra. See DOI
10.1039/c3cc48929a
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc48929a