Multistep soft chemistry method for valence reduction in transition metal oxides with triangular (CdI2-type) layersElectronic supplementary information (ESI) available: Full experimental details, PXD patterns of prepared phases, particle size information, SEM images, Li1+/Na1+ intercalation rates, DSC curve, crystal structures description. See DOI: 10.1039/c3cc48836e

Transition metal (M) oxides with MO 2 triangular layers demonstrate a variety of physical properties depending on the metal oxidation states. In the known compounds, metal oxidation states are limited to either 3+ or mixed-valent 3+/4+. A multistep soft chemistry synthetic route for novel phases wit...

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Bibliographic Details
Main Authors Blakely, Colin K, Bruno, Shaun R, Poltavets, Viktor V
Format Journal Article
LanguageEnglish
Published 13.02.2014
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Summary:Transition metal (M) oxides with MO 2 triangular layers demonstrate a variety of physical properties depending on the metal oxidation states. In the known compounds, metal oxidation states are limited to either 3+ or mixed-valent 3+/4+. A multistep soft chemistry synthetic route for novel phases with M 2+/3+ O 2 triangular layers is reported. A multistep soft chemistry synthetic route for a novel family of transition metal (M) oxides with M 2+ / 3+ O 2 triangular (CdI 2 -type) layers is reported.
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Electronic supplementary information (ESI) available: Full experimental details, PXD patterns of prepared phases, particle size information, SEM images, Li
intercalation rates, DSC curve, crystal structures description. See DOI
10.1039/c3cc48836e
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc48836e