Enantioselective synthesis of helical polydiacetylenes in the visible light regionElectronic supplementary information (ESI) available. See DOI: 10.1039/c3cc48478e

Herein, we demonstrate for the first time that the enantio-selective polymerization of DA monomers could be realized upon irradiation with circularly polarized visible light (CPVL), which could effectively provide chiral order in the propagating step of a polymerization reaction. The interaction bet...

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Main Authors Yang, Guang, Han, Lu, Jiang, Hao, Zou, Gang, Zhang, Qijin, Zhang, Douguo, Wang, Pei, Ming, Hai
Format Journal Article
LanguageEnglish
Published 04.02.2014
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Summary:Herein, we demonstrate for the first time that the enantio-selective polymerization of DA monomers could be realized upon irradiation with circularly polarized visible light (CPVL), which could effectively provide chiral order in the propagating step of a polymerization reaction. The interaction between CPVL and the PDA oligomer was assumed to play a dominant role in the enantio-selective polymerization process.
Bibliography:10.1039/c3cc48478e
Electronic supplementary information (ESI) available. See DOI
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc48478e