Reactivity of a fac-ReCl(α-diimine)(CO)3 complex with an NAD+ model ligand toward CO2 reductionElectronic supplementary information (ESI) available. See DOI: 10.1039/c3cc47699e

The reactivity of a rhenium complex containing an NAD + model ligand was examined toward photochemical formation of the corresponding NADH-like dihydro form of the complex and electrochemical CO 2 reduction. The hydricity of the NADH-like complex was estimated by a thermodynamic cycle and reaction w...

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Main Authors Matsubara, Yasuo, Hightower, Sean E, Chen, Jinzhu, Grills, David C, Polyansky, Dmitry E, Muckerman, James T, Tanaka, Koji, Fujita, Etsuko
Format Journal Article
LanguageEnglish
Published 12.12.2013
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Summary:The reactivity of a rhenium complex containing an NAD + model ligand was examined toward photochemical formation of the corresponding NADH-like dihydro form of the complex and electrochemical CO 2 reduction. The hydricity of the NADH-like complex was estimated by a thermodynamic cycle and reaction with Ph 3 C + . A rhenium complex containing an NADH-like model ligand has been prepared and used for electrochemical CO 2 reduction.
Bibliography:10.1039/c3cc47699e
Electronic supplementary information (ESI) available. See DOI
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc47699e