Reactivity of a fac-ReCl(α-diimine)(CO)3 complex with an NAD+ model ligand toward CO2 reductionElectronic supplementary information (ESI) available. See DOI: 10.1039/c3cc47699e
The reactivity of a rhenium complex containing an NAD + model ligand was examined toward photochemical formation of the corresponding NADH-like dihydro form of the complex and electrochemical CO 2 reduction. The hydricity of the NADH-like complex was estimated by a thermodynamic cycle and reaction w...
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Main Authors | , , , , , , , |
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Format | Journal Article |
Language | English |
Published |
12.12.2013
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Online Access | Get full text |
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Summary: | The reactivity of a rhenium complex containing an NAD
+
model ligand was examined toward photochemical formation of the corresponding NADH-like dihydro form of the complex and electrochemical CO
2
reduction. The hydricity of the NADH-like complex was estimated by a thermodynamic cycle and reaction with Ph
3
C
+
.
A rhenium complex containing an NADH-like model ligand has been prepared and used for electrochemical CO
2
reduction. |
---|---|
Bibliography: | 10.1039/c3cc47699e Electronic supplementary information (ESI) available. See DOI |
ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/c3cc47699e |