Decomposition of hydrazine by an organic fullerene-phthalocyanine p-n bilayer photocatalysis system over the entire visible-light regionElectronic supplementary information (ESI) available: Experimental details, structural information, illustration of a twin-compartment cell employed for photoelectrolysis, cyclic voltammograms, photoelectrolysis data for N2H4 decomposition with respect to applied potentials, photocatalysis data for N2H4 decomposition with respect to light intensity and film thic

An organic p-n bilayer photocatalysis system successfully induced the oxidative decomposition of hydrazine (N 2 H 4 ) into N 2 and simultaneously yielded H 2 from H + . This demonstrates the first instance of the stoichiometric decomposition of N 2 H 4 under visible-light irradiation. An organophoto...

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Bibliographic Details
Main Authors Abe, Toshiyuki, Taira, Naohiro, Tanno, Yoshinori, Kikuchi, Yuko, Nagai, Keiji
Format Journal Article
LanguageEnglish
Published 28.01.2014
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Summary:An organic p-n bilayer photocatalysis system successfully induced the oxidative decomposition of hydrazine (N 2 H 4 ) into N 2 and simultaneously yielded H 2 from H + . This demonstrates the first instance of the stoichiometric decomposition of N 2 H 4 under visible-light irradiation. An organophotocatalysis system featuring a p-n bilayer induces the stoichiometric decomposition of hydrazine under the full irradiation of visible-light.
Bibliography:10.1039/c3cc46701e
decomposition with respect to light intensity and film thickness of the photocatalyst device C
2
4
ZnPc/Nf, and the energy diagram for N
Electronic supplementary information (ESI) available: Experimental details, structural information, illustration of a twin-compartment cell employed for photoelectrolysis, cyclic voltammograms, photoelectrolysis data for N
H
60
decomposition in the present photocatalysis system. See DOI
decomposition with respect to applied potentials, photocatalysis data for N
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc46701e