Pd-catalyzed synthesis of symmetrical and unsymmetrical siloxanesElectronic supplementary information (ESI) available: Detailed experimental procedures and copies of 1H and 13C NMR. See DOI: 10.1039/c3cc46294c

A palladium-catalyzed arylation of hydrosiloxanes was developed for the synthesis of symmetrical and unsymmetrical siloxanes. Reactive functional moieties such as hydroxy or cyano groups were able to tolerate the reaction conditions and several novel unsymmetrical siloxanes were synthesized in moder...

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Bibliographic Details
Main Authors Kurihara, Yu, Yamanoi, Yoshinori, Nishihara, Hiroshi
Format Journal Article
LanguageEnglish
Published 07.11.2013
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Summary:A palladium-catalyzed arylation of hydrosiloxanes was developed for the synthesis of symmetrical and unsymmetrical siloxanes. Reactive functional moieties such as hydroxy or cyano groups were able to tolerate the reaction conditions and several novel unsymmetrical siloxanes were synthesized in moderate to high yield. A palladium-catalyzed arylation of hydrosiloxanes was developed for the synthesis of symmetrical and unsymmetrical siloxanes.
Bibliography:1
13
C NMR. See DOI
H and
10.1039/c3cc46294c
Electronic supplementary information (ESI) available: Detailed experimental procedures and copies of
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc46294c