Highly diastereoselective radical cyclisations of chiral sulfiniminesElectronic supplementary information (ESI) available: Full experimental details. CCDC 952387-952390. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3cc45452e

Chiral amines are formed by the highly diastereoselective intramolecular addition of alkyl and aryl radicals onto chiral mesityl sulfinimines. Cyclisation of aryl and alkyl radicals with tethered chiral mesitylsulfinimines is found to proceed with exquisite diastereoselectivity.

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Main Authors Rochette, Elise M, Lewis, William, Dossetter, Al G, Stockman, Robert A
Format Journal Article
LanguageEnglish
Published 19.09.2013
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Abstract Chiral amines are formed by the highly diastereoselective intramolecular addition of alkyl and aryl radicals onto chiral mesityl sulfinimines. Cyclisation of aryl and alkyl radicals with tethered chiral mesitylsulfinimines is found to proceed with exquisite diastereoselectivity.
AbstractList Chiral amines are formed by the highly diastereoselective intramolecular addition of alkyl and aryl radicals onto chiral mesityl sulfinimines. Cyclisation of aryl and alkyl radicals with tethered chiral mesitylsulfinimines is found to proceed with exquisite diastereoselectivity.
Author Lewis, William
Dossetter, Al G
Stockman, Robert A
Rochette, Elise M
AuthorAffiliation AstraZeneca
University of Nottingham
School of Chemistry
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  givenname: William
  surname: Lewis
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  givenname: Al G
  surname: Dossetter
  fullname: Dossetter, Al G
– sequence: 4
  givenname: Robert A
  surname: Stockman
  fullname: Stockman, Robert A
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Notes For ESI and crystallographic data in CIF or other electronic format see DOI
Electronic supplementary information (ESI) available: Full experimental details. CCDC
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  publication-title: Chiral Amine Synthesis: Developments and Applications
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Snippet Chiral amines are formed by the highly diastereoselective intramolecular addition of alkyl and aryl radicals onto chiral mesityl sulfinimines. Cyclisation of...
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Title Highly diastereoselective radical cyclisations of chiral sulfiniminesElectronic supplementary information (ESI) available: Full experimental details. CCDC 952387-952390. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3cc45452e
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