Highly diastereoselective radical cyclisations of chiral sulfiniminesElectronic supplementary information (ESI) available: Full experimental details. CCDC 952387-952390. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3cc45452e

Chiral amines are formed by the highly diastereoselective intramolecular addition of alkyl and aryl radicals onto chiral mesityl sulfinimines. Cyclisation of aryl and alkyl radicals with tethered chiral mesitylsulfinimines is found to proceed with exquisite diastereoselectivity.

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Bibliographic Details
Main Authors Rochette, Elise M, Lewis, William, Dossetter, Al G, Stockman, Robert A
Format Journal Article
LanguageEnglish
Published 19.09.2013
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Summary:Chiral amines are formed by the highly diastereoselective intramolecular addition of alkyl and aryl radicals onto chiral mesityl sulfinimines. Cyclisation of aryl and alkyl radicals with tethered chiral mesitylsulfinimines is found to proceed with exquisite diastereoselectivity.
Bibliography:For ESI and crystallographic data in CIF or other electronic format see DOI
Electronic supplementary information (ESI) available: Full experimental details. CCDC
10.1039/c3cc45452e
952387-952390
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc45452e