Room temperature C-H bond activation on a [PdI-PdI] platformElectronic supplementary information (ESI) available: Detailed synthetic procedures, characterization data, X-ray details and CIF files for all compounds. CCDC 940018-940020, 952838 and 952839. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3cc44493g

Heteroatom assisted C-H bond activation of 2-substituted naphthyridines with solvated Pd I 2 (CH 3 CN) 6 (BF 4 ) 2 provides bi- and trinuclear Pd II cyclometalated complexes, which provide valuable insight into potential intermediates in palladium catalyzed direct arylation reactions. Regioselective...

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Bibliographic Details
Main Authors Sarkar, Mithun, Doucet, Henri, Bera, Jitendra K
Format Journal Article
LanguageEnglish
Published 26.09.2013
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Summary:Heteroatom assisted C-H bond activation of 2-substituted naphthyridines with solvated Pd I 2 (CH 3 CN) 6 (BF 4 ) 2 provides bi- and trinuclear Pd II cyclometalated complexes, which provide valuable insight into potential intermediates in palladium catalyzed direct arylation reactions. Regioselective heteroaryl C-H/Br activation is achieved on a [Pd I -Pd I ] platform under mild conditions.
Bibliography:952838
For ESI and crystallographic data in CIF or other electronic format see DOI
and
940018-940020
10.1039/c3cc44493g
Electronic supplementary information (ESI) available: Detailed synthetic procedures, characterization data, X-ray details and CIF files for all compounds. CCDC
,
952839
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc44493g