Isostructural salts of the same complex showing contrasting thermal spin-crossover mediated by multiple phase changesCelebrating 300 years of Chemistry at Edinburgh.Electronic Supplementary Information (ESI) available: Experimental descriptions, crystallographic figures and tables, and additional powder diffraction data. CCDC 936803936805. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3cc43613f

Two salts of [FeL 2 ] 2+ (L = 2,6-bis[5-methyl-1 H -pyrazol-3-yl]pyridine) are isostructural under ambient conditions but show different thermal spin-crossover behaviour, involving a variety of crystallographic phase changes. The salts [FeL 2 ]X 2 (L = 2,6-bis[5-methyl-1 H -pyrazol-3-yl]pyridine, X...

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Bibliographic Details
Main Authors Roberts, Thomas D, Little, Marc A, Tuna, Floriana, Kilner, Colin A, Halcrow, Malcolm A
Format Journal Article
LanguageEnglish
Published 18.06.2013
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Summary:Two salts of [FeL 2 ] 2+ (L = 2,6-bis[5-methyl-1 H -pyrazol-3-yl]pyridine) are isostructural under ambient conditions but show different thermal spin-crossover behaviour, involving a variety of crystallographic phase changes. The salts [FeL 2 ]X 2 (L = 2,6-bis[5-methyl-1 H -pyrazol-3-yl]pyridine, X = BF 4 or ClO 4 ) are isostructural under ambient conditions but show different spin-state behaviour in their hydrated and anhydrous forms, involving a variety of crystallographic phase changes.
Bibliography:For ESI and crystallographic data in CIF or other electronic format see DOI
936803936805
10.1039/c3cc43613f
Celebrating 300 years of Chemistry at Edinburgh.
Electronic Supplementary Information (ESI) available: Experimental descriptions, crystallographic figures and tables, and additional powder diffraction data. CCDC
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc43613f